Of the vices embodied by the standard Dragon Age demons -- rage, hunger, sloth, desire, and pride -- I'd probably be most tempted by sloth. No one who mostly knows me online believes this, but I am, in fact, incredibly lazy. I avoid chores and errands, put the bare minimum of effort into a lot of things, and am almost always happy to spend a weekend kicking back on the couch with TV or a book or games or the Internet. So if a sloth demon came along and offered me some kind of deal where I'd never have to do housework again, or go grocery shopping, or deal with any of my inane tasks at work, I'd take it in a second.
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